摘要:通過(guò)分析國(guó)內(nèi)外碳酸二甲酯生產(chǎn)工藝的現(xiàn)狀,采用尿素醇解法來(lái)生產(chǎn)碳酸二甲酯,針對(duì)目前生產(chǎn)工藝中存在的幾個(gè)難點(diǎn)問(wèn)題進(jìn)行工藝的改進(jìn),采用Aspen 軟件對(duì)年產(chǎn) 1.5 萬(wàn)噸碳酸二甲酯生產(chǎn)工藝進(jìn)行了模擬計(jì)算,經(jīng)過(guò)改進(jìn)后的生產(chǎn)工藝可使碳酸二甲酯的純度達(dá)到 99.8%,通過(guò)分析目前市場(chǎng)行情估算整個(gè)項(xiàng)目的經(jīng)濟(jì)投資,通過(guò) Aspen 軟件對(duì)整個(gè)流程進(jìn)行物料衡算,熱量衡算,設(shè)備的計(jì)算等。關(guān)鍵詞:碳酸二甲酯;尿素醇解法;生產(chǎn)工藝;Aspen 軟件;經(jīng)濟(jì)分析; Abstract: Analyse DMC production technology at home and abroad, using Urea alcoholysis to produce DMC. To improve technology to solve some promble which exist presently. Using Aspen software to simulate technology flow of DMC. After the production technololy’s ameliorate, the DMC content is reach at 99.8%. Estimate economy of the whole project through market analysis. Using Aspen software to get material balance, heat balance and equipment data etc.Keywords: DMC; Urea alcoholysis;Production technology; Aspen software; Economy analysis目 錄1 總論 ............................................................................................................................11.1 碳酸二甲酯的性質(zhì)和用途 ................................................................................................................11.2 碳酸二甲酯的市場(chǎng)分析 ....................................................................................................................11.2.1 國(guó)外產(chǎn)能情況及需求預(yù)測(cè) ..........................................................................................................11.2.2 國(guó)內(nèi)產(chǎn)能情況及需求預(yù)測(cè) ..........................................................................................................11.2.3 廠址選擇 ......................................................................................................................................12 碳酸二甲酯生產(chǎn)工藝 ................................................................................................22.1 工藝方案的選擇 .................................................................................................................................22.2 碳酸二甲酯生產(chǎn)工藝 ........................................................................................................................22.2.1 反應(yīng)流程 .....................................................................................................................................22.2.2 反應(yīng)條件及能耗 ..........................................................................................................................32.2.3 反應(yīng)主要設(shè)備 ..............................................................................................................................32.2.4 催化劑的比較與選擇 ..................................................................................................................32.2.5 膜的要求 .....................................................................................................................................32.2.6 膜的選擇 ......................................................................................................................................43 投資與經(jīng)濟(jì)分析 ........................................................................................................63.1 總投資 .................................................................................................................................................63.1.1 總設(shè)備投資費(fèi)用計(jì)算 ..................................................................................................................63.1.2 其它固定資產(chǎn)投資 ......................................................................................................................83.1.3 固定資產(chǎn)折舊費(fèi) .........................................................................................................................83.1.4 維修費(fèi)用 .....................................................................................................................................93.1.5 原料費(fèi)用 .....................................................................................................................................93.1.6 人事費(fèi)用 .....................................................................................................................................93.1.7 能源的消耗 ................................................................................................................................113.1.8 無(wú)形資產(chǎn) ...................................................................................................................................123.1.9 總投資費(fèi)用 ...............................................................................................................................123.2 總收益估算 .......................................................................................................................................123.2.1 投資額的確定 ...........................................................................................................................123.3 資金籌措 ...........................................................................................................................................133.4 經(jīng)濟(jì)分析 ...........................................................................................................................................133.4.1 投資回收期 ................................................................................................................................133.4.2 投資凈現(xiàn)值 ...............................................................................................................................133.4.3 內(nèi)部收益率 ...............................................................................................................................134 物料衡算 ..................................................................................................................134.1 流程簡(jiǎn)述 ...........................................................................................................................................134.2 碳酸二甲酯合成及分離工段 ...........................................................................................................134.3 反應(yīng)精餾塔物料衡算 .......................................................................................................................144.4 共沸精餾塔物料衡算 .......................................................................................................................154.5 膜分離器物料衡算 ..........................................................................................................................154.6 萃取精餾塔物料衡算 .......................................................................................................................164.7 萃取劑回收塔物料衡算 ...................................................................................................................164.8 DMC 精制塔物料衡算 .....................................................................................................................174.9 甲醇精制塔物料衡算 .......................................................................................................................184.10 總流程物料衡算 .............................................................................................................................185 熱量衡算 ..................................................................................................................205.1 HEATER1 熱量衡算 .........................................................................................................................205.2 HEATER2 熱量衡算 .........................................................................................................................205.3 CONDENSE 熱量衡算 .....................................................................................................................215.4 HEATX1 熱量衡算 ...........................................................................................................................225.5 HEATX2 熱量衡算 ...........................................................................................................................225.6 SEP1 熱量衡算 ..................................................................................................................................235.7 SEP2 熱量衡算 ..................................................................................................................................235.8 T1 熱量衡算 ......................................................................................................................................245.9 T2 熱量衡算 ......................................................................................................................................255.10 T3 熱量衡算 ....................................................................................................................................255.11 T4 熱量衡算 ....................................................................................................................................265.12 T5 熱量衡算 ....................................................................................................................................276 主要設(shè)備設(shè)計(jì)與選型 ..............................................................................................286.1 泵的選型舉例 ..................................................................................................................................286.2 換熱器的選型舉例 ..........................................................................................................................346.3 精餾塔的設(shè)計(jì)舉例 ..........................................................................................................................366.3.1 精餾塔 T1 設(shè)計(jì)數(shù)據(jù) ..................................................................................................................366.3.2 精餾塔 T2 設(shè)計(jì)數(shù)據(jù) .................................................................................................................386.3.3 精餾塔 T5 設(shè)計(jì)數(shù)據(jù) .................................................................................................................406.2 非標(biāo)準(zhǔn)設(shè)備設(shè)計(jì) ..............................................................................................................................436.2.1 反應(yīng)精餾塔 ...............................................................................................................................436.2.2 尿素熔融裝置 ...........................................................................................................................446.3 設(shè)備一覽表 ......................................................................................................................................457 管道特性表 ..............................................................................................................47參考文獻(xiàn) ......................................................................................................................49謝 辭 ......................................................................................................................51附圖一:帶控制點(diǎn)工藝流程圖附圖二:反應(yīng)精餾塔裝置圖附圖三:萃取精餾塔裝置圖附圖四:尿素熔融裝置圖附圖五:換熱器裝置圖附圖六:總廠平面圖1